column 7 of the hazardous materials table

9 Packaging for certain PCBs for disposal and storage is prescribed by EPA in 40 CFR 761.60 and 761.65. Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. will also bring you to search results. The Electronic Code of Federal Regulations (eCFR) is a continuously updated online version of the CFR. that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. N25 Steel single packagings are not authorized. No more than four bottles, securely closed with threaded caps, may be packed in each box. meet the venting requirements in 173.24(g) or (2.) result, it may not include the most recent changes applied to the CFR. Column 7: Special provisions. c. The completed package must meet the Packing Group II performance level, as applicable for combination packagings with a plastic box outer packaging, in accordance with subpart M of part 178 of this subchapter. In addition, packages shall be legibly and durably marked with an identification of the consignor, the consignee, or both. This is in response to your November 18, 2015 e-mail and subsequent conversations with members of my staff requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the selection of a . Except when approved by the Associate Administrator, these items may only contain hazardous materials for which exceptions are referenced in Column (8) of the 172.101 Table and are provided in part 173, subparts D and G, of this subchapter. For criteria in determining what is a new lighter design, see 173.308(b)(1). Lading must be blanketed at all times with a dry inert gas at a pressure not to exceed 103 kPa (15 psig). Bulk packagings must have exterior heating coils fusion welded to the tank shell which have been properly stress relieved. B25 Packagings must be made from monel or nickel or monel-lined or nickel-lined steel. A101 In addition to the applicable requirements of 173.185, the quantity of lithium metal in the batteries contained in any piece of equipment must not exceed 12 g per cell and 500 g per battery. (h) Column 7: Special provisions. A82 The quantity limits in columns (9A) and (9B) do not apply to human or animal body parts, whole organs or whole bodies known to contain or suspected of containing an infectious substance. For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N, of this subchapter. B132 Except for transportation by aircraft, UN2813, Water reactive solid, n.o.s. **Self-reactive materials that are thermally unstable and that 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. These provisions apply only to transportation by water: W1 This substance in a non friable prill or granule form is not subject to the requirements of this subchapter when tested in accordance with the UN Manual of Test and Criteria (IBR, see 171.7 of this subchapter) and is found to not meet the definition or criteria for inclusion in Division 5.1. See 173.306(h) of this subchapter. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. N85 Packagings certified at the Packing Group I performance level may not be used. 40 Polyester resin kits consist of two components: A base material (either Class 3 or Division 4.1, Packing Group II or III) and an activator (organic peroxide), each separately packed in an inner packaging. These provisions apply only to transportation in IBCs and Large Packagings. For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). 346 Nitrogen, refrigerated liquid (cryogenic liquid), UN1977 transported in accordance with the requirements for open cryogenic receptacles in 173.320 and this special provision are not subject to any other requirements of this subchapter. When portable tank instruction T75 is referenced in Column (7) of the 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of 178.277 of this subchapter. A separate drafting site Individual Name: Mr. David Comen. This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. Outage must be at least 5 percent at 98 C (208 F). 388 a. Lithium batteries containing both primary lithium metal cells and rechargeable lithium ion cells that are not designed to be externally charged, must meet the following conditions: i. For the purpose of this special provision, vehicles are self-propelled apparatus designed to carry one or more persons or goods. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. 421 This entry will no longer be effective on January 2, 2023, unless we terminate it earlier or extend it beyond that date by notice of a final rule in the Federal Register. B83 Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in concentrations over 65.25 percent. A20 Plastic bags as inner receptacles of combination packagings are not authorized for transportation by aircraft. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. A200 These articles must be transported as cargo and may not be carried aboard an aircraft by passengers or crewmembers in carry-on baggage, checked baggage, or on their person unless specifically authorized in 175.10. The articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions specified in 173.63(a) of this subchapter are met. B66 Each tank must be equipped with gas tight valve protection caps. Comments or questions about document content can not be answered by OFR staff. The tank must have been designed and constructed to be capable of withstanding full vacuum. Radiation detection systems containing such detectors are not subject to any other requirements of this subchapter provided they are packed in accordance with paragraph c of this special provision. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. Please do not provide confidential The outside of each package must be plainly marked ARTICLES, EXPLOSIVES, N.O.S. Prior to repacking into the life-saving appliance, an installed inflation cylinder must successfully meet and pass all inspection and test criteria and standards of the raft manufacturer and the vessel Flag State requirements for cylinders installed as part of life-saving appliances, self-inflating (UN2990) used on marine vessels. TP12 This material is considered highly corrosive to steel. is available with paragraph structure matching the official CFR For UN2031 with more than 55% nitric acid, rigid plastic IBCs and composite IBCs with a rigid plastic inner receptacle are authorized for two years from the date of IBC manufacture. TP32 Portable tanks may be used subject to the following conditions: a. In addition, a lighter design intended to contain a non-pressurized Class 3 material is excepted from the examination and testing criteria specified in 173.308(b)(3). 171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in 173.127. Pressing enter in the search box 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. 164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 336 The use of UN1H1 drums, UN3H1 jerricans, and UN6HA1 composite packagings which meet the requirements of part 178 of the HMR at the Packing Group I or II performance level. user convenience only and is not intended to alter agency intent B55 Water-tight, sift-proof, closed-top, metal-covered hopper cars, equipped with a venting arrangement (including flame arrestors) approved by the Associate Administrator are also authorized. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). 2 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. Use of these proper shipping names for domestic shipments may be made only under a DOT special permit, as defined in, and in accordance with the requirements of subpart B of part 107 of this subchapter. TP17 Only inorganic non-combustible materials may be used for thermal insulation of the tank. Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. B27 Tanks must have a service pressure of 1,034 kPa (150 psig). N90 Metal packagings are not authorized. N86 UN pressure receptacles made of aluminum alloy are not authorized. 11 The hazardous material must be packaged as either a liquid or a solid, as appropriate, depending on its physical form at 55 C (131 F) at atmospheric pressure. The proper shipping name Paint related material may be used for consignments of packages containing Paint and Paint related material in the same package; b. 332 Magnesium nitrate hexahydrate is not subject to the requirements of this subchapter. a. 337 Authorizes the use of regulated waste containers manufactured prior to October 1, 2006 to be marked with the alternative shipping name of Regulated medical waste, UN3291 and arrows that deviate as prescribed in 172.312(a)(2) in that they may be black or white. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit must use the proper shipping name Lithium batteries installed in cargo transport unit found in the 172.101 Hazardous Materials Table. 140 This material is regulated only when it meets the defining criteria for a hazardous substance or a marine pollutant. c. Every installed inflation cylinder, as associated equipment of the life-saving appliance, must be packed within the protective packaging of the life raft and the life raft itself must otherwise be in compliance with 173.219. d. The serial number for each cylinder must be recorded as part of the life-saving appliance service record by the U.S. Coast Guard-approved servicing facility. Tank car tanks must have a test pressure rating of 1,379 kPa (200 psig). Any glass inner packaging showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision; b. Transportation of these packages also requires the door of each van trailer to be marked with Warning trailer may contain chemical vapor. The Associate Administrator will base the authorization on results from Series 2 tests and a Series 6(c) test from the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) on packages as prepared for transport in accordance with the requirements of this subchapter. B65 Tank cars constructed before March 16, 2009, must have a test pressure of 34.47 Bar (500 psig) or greater and conform to Class 105A. 385 Notwithstanding the provisions of 177.834(l) of this subchapter, cargo heaters may be used when weather conditions are such that the freezing of a wetted explosive material is likely. Column 7 specifies codes for special provisions applicable to hazardous materials. For other than Class 7 or the DANGEROUS . However, sediments remaining in the tank that meet the definition for a hazardous material are subject to the applicable regulations of this subchapter. R1 A person who offers for transportation tank cars containing sulfur, molten or residue of sulfur, molten may reference the Sulfur Institute's, Molten Sulphur Rail Tank Car Guidance document (see 171.7 of this subchapter) to identify tank cars that may pose a risk in transportation due to the accumulation of formed, solid sulfur on the outside of the tank. B44 All parts of valves and safety relief devices in contact with lading must be of a material which will not cause formation of acetylides. An important, but often overlooked, requirement for the safe and regulatory compliant transportation of a HazMat is an understanding of the special provisions in column 7 of the Hazardous Materials Table. With less than 10 percent formaldehyde, are not subject to this subchapter. This molecular arrangement is exactly the same as that for dithioketo QA [5]. For non-pressurized lighters containing a Class 3 (flammable liquid) material, its design, description, and packaging must be approved by the Associate Administrator prior to being offered for transportation or transported in commerce. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. If appropriate, a package containing this material must conform to the additional labeling requirements of 172.402 of this subchapter. If a tank car tank is equipped with a reclosing pressure relief valve, the tank must also be equipped with a vacuum relief valve. This entry may only be used for the transport of non-activated batteries that contain dry potassium hydroxide and that are intended to be activated prior to use by the addition of an appropriate amount of water to the individual cells. N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. Displaying title 49, up to date as of 3/02/2023. N12 Plastic packagings are not authorized. Table 1 authorizes IBCs for specific proper shipping names through the use of IB Codes assigned in the 172.101 table of this subchapter. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. After unloading, the residual material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. Each inner packaging is contained in a sealed leak-proof intermediate packaging with sufficient absorbent material capable of containing the contents of the inner packaging; c. Intermediate packagings are securely packed in an outer packaging of a type permitted by 173.158(g) of this subchapter which meet the requirements of part 178 of this subchapter at the Packing Group I performance level; d. The maximum quantity of nitric acid in the package does not exceed 300 mL; and. Packagings must be so constructed that explosion is not possible by reason of increased internal pressure. No outage is required for helium. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. A53 Refrigerating machines and refrigerating machine components are not subject to the requirements of this subchapter when containing less than 12 kg (26.4 pounds) of a non-flammable gas or when containing 12 L (3 gallons) or less of ammonia solution (UN2672) (see 173.307 of this subchapter). Examples of equipment are lawnmowers, cleaning machines, or model boats and model aircraft. When a special provision specifies packaging or packaging requirements - Except for a portable tank containing refrigerated liquefied helium, a portable tank shall have an outage of at least two percent below the inlet of the pressure relief device or pressure control valve, under conditions of incipient opening, with the portable tank in a level attitude. This includes vehicles transported in a packaging. Such articles must comply with the following requirements: (1) The water capacity of the pressure receptacle must not exceed 0.5 L and the working pressure must not exceed 25 bar at 15 C (59 F); (2) The minimum burst pressure of the pressure receptacle must be at least four times the pressure of the gas at 15 C (59 F); (3) Each article must be manufactured in such a way that unintentional firing or release is avoided under normal conditions of handling, packing, transport and use. Each special provision is indicated using a numeric or alphanumeric code. For portable tanks used for the transport of refrigerated liquefied helium and refrigerated liquefied atmospheric gas (except oxygen), the maximum rate at which the tank is filled must not exceed the liquid flow capacity of the pressure relief device rated at 130 percent of the portable tank's design pressure. b. B15 Packagings must be protected with non-metallic linings impervious to the lading or have a suitable corrosion allowance. These detectors must have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and. Unless otherwise provided in this subchapter, these special provisions do not apply to UN, IM Specification portable tanks or IBCs. N92 Notwithstanding the provisions of 173.24(g) of this subchapter, packagings shall be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. N4 For combination or composite packagings, glass inner packagings, other than ampoules, are not permitted. N87 The use of copper valves on UN pressure receptacles is prohibited. 4 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone D (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. 166 When transported in non-friable tablet form, calcium hypochlorite, dry, may be transported as a Packing Group III material. Alcoholic beverages containing more than 24 percent but not more than 70 percent alcohol by volume must be transported as materials in Packing Group III. Tanks containing solidified methacrylic acid must not be reheated during transport. Symbols, if used, must be registered with the Associate Administrator. Filling limits must be in accordance with portable tank special provision TP3. Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). Table 2 defines IP Codes on the use of IBCs that are assigned to specific commodities in the 172.101 Table of this subchapter. 125 Lactose or glucose or similar materials may be used as a phlegmatizer provided that the substance contains not less than 90%, by mass, of phlegmatizer. (4) Each detector must be tested to a 1 1010 cm3/s leaktightness standard before filling. A6 For combination packagings, if plastic inner packagings are used, they must be packed in tightly closed metal receptacles before packing in outer packagings. B26 Tanks must be insulated. Specification 110A500W tanks must be stainless steel. TP19 The calculated wall thickness must be increased by 3 mm at the time of construction. (c)Column 2: Hazardous materials descriptions and proper shipping names. TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. TP6 The tank must be equipped with a pressure release device which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported. However, the hazard label corresponding to the hazard class or division may be substituted for the marking. A54 Irrespective of the quantity limits in Column 9B of the 172.101 table, a lithium battery, including a lithium battery packed with, or contained in, equipment that otherwise meets the applicable requirements of 173.185, may have a mass exceeding 35 kg if approved by the Associate Administrator prior to shipment. 15, 1976, unless otherwise noted. 106 The recognized name of the particular explosive may be specified in addition to the type. B90 Steel tanks conforming or equivalent to ASME specifications which contain solid or semisolid residual motor fuel antiknock mixture (including rust, scale, or other contaminants) may be shipped by rail freight or highway. (iii) Constructing the battery with terminals that are recessed or otherwise protected so that the terminals will not be subjected to damage if the package is dropped. Columns 8A, 8B and 8C specify the applicable sections for . Placards may be displayed for a hazardous material, even when not required, if the placarding otherwise conforms to the requirements of Subpart F of Part 172 [172.502(c)]. The only tank car tanks authorized are Class DOT 105 tank cars having a test pressure of 2,069 kPa (300 psig) or greater. A combination packaging consisting of a 4G fiberboard box with inner receptacles of glass or earthenware; b. The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Net weight of contents in fiberboard boxes may not exceed 29 kg (64 pounds). When a plus sign is assigned to mix- A 25 mm (1 inch) woven lining of asbestos or other approved material must be placed between the bolster slabbing and the bottom of the tank. 172.101 Hazardous Materials Table (HMT). N6 Battery fluid packaged with electric storage batteries, wet or dry, must conform to the packaging provisions of 173.159 (g) or (h) of this subchapter. 176 This entry must be used for formaldehyde solutions containing methanol as a stabilizer. ); and. B135 For Large Packagings offered for transport by vessel, flexible or fibre inner packagings shall be hermetically sealed. Rigid plastics: 11H1, 11H2, 21H1 and 21H2, c. Composite with plastic inner receptacle: 11HZ1, 11HZ2, 21HZ1 and 21HZ2, e. Wooden: 11C, 11D and 11F (with inner liners). Thickness of stainless steel for tank shell and heads for cargo tanks and portable tanks must be the greater of 7.62 mm (0.300 inch) or the thickness required for a tank with a design pressure at least equal to 1.5 times the vapor pressure of the lading at 46 C (115 F). Using the nominal capacitance (CN), rated voltage (UR) and the rated lower limit voltage (UL). e. Transport in accordance with this special provision must be noted on the shipping paper. If a package contains both lithium metal batteries and lithium ion batteries packed with and contained in equipment, the package must be marked as required for both battery types.

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